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i have a few questions dealing with calcium chloride and ammonia....can you help?

1)what volume of calcium chloride holds a pound of ammonia? (i really need a graph chart covering temprature /pressure)

2) does the electrical resistance of calcium chlride change as it becomes satureted with ammonia?

i really need some help with this....i have been unable to find any temp/pressure graph charts dealing with ammonia saturated calcium chloride. im in the process of trying to build a solar powered air conditioner with a bank of generator/absorber cells,an air cooled tower condensor, a large liquid ammonia reciever, an ammonia evaporator/glycol heat exchanger, and finally a gravity fed glycol/room ait heat exchanger.

yes, i am fammiliar with the dangerous pressures that will be generated. i know that ammonia is nasty stuff, and i understand basic thermodynamics (i install and fix air conditioners for a living)

i just need help with the chemistry end of the thing.

with gratitude,
Possum

ps.....please feel free to IM or email me (in my bio)

The answers for your questions must be determined experimentally. I can only give you some theory behind the answer below.

Calcium chloride can react with ammonia gas to gaive a stable compound with the formula CaCl2*8NH3

This means one mole of Calcium chloride will adsorb 8 moles of Ammonia. This means that about 111 grams of anhydrous (bone dry) calcium chloride will adsorb 8 (17) = 136 grams of Ammonia.

136 g / 454 g/lb = 0.300 lb of Ammonia for about every 111 g / 454 g/lb = 0.25 pounds of dry Calcium chloride.

I am sure that the electrical resistance would change but you would need to take experimental readings to see how much.

A mixture of CaCl2 plus CaBr2 seem to be better for Ammonia storage, but may be more expensive.

07 Human Design Emotional Center

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